Reactive Gases and the Synthetic Lubricants that Love Them

Fluorine is a remarkable element. In its elemental state,friction while not succumbing to the fierce oxidization
it is highly reactive and toxic. However, when tightlyand other violent reactions that characterize many
bonded to other molecules and elements, it becomessuch gases.
almost totally non-reactive, taking on remarkableLife support systems that carry oxygen (and often
properties that have made the manufacture of almostnitrogen, too) in medical applications must meet the
totally inert lubricants possible. These lubricants not onlyhighest standards of oxygen safety. Only totally inert
include high temperature grease and oil but alsosubstances are allowed, even inside sealed bearings
several types of wax.and the other hardware of an oxygen delivery system.
Fluorine and hydrogen fluoride have a remarkableOxygen compatibility of halocarbon synthetic, inert oils
affinity for calcium and silicon. This property allowsand waxes has been investigated and approved for
these simple fluoro-acids to do very useful things, suchuse by notoriously picky EU investigation bodies. These
as etch glass (which is made from silicon-based silica)arbiters of oxygen safety concerned themselves with
in an industrial setting. It also makes it very dangerous.all types and sizes of oxygen delivery systems.
That very same acid can burn right through your armOxygen safety, especially in extreme circumstances
and straight to your bones.such as those often encountered by portable oxygen
Of course, most people don't handle highly reactiveunits, depends upon it. Consider how such tanks can
fluorochemicals at any point in their lives. This isbe inadvertently knocked around and tossed about
reserved for a very small number of researchers andwhile being delivered.
technicians who are well aware of the danger suchThough the larger bullet shaped tanks are usually not
compounds of fluorine pose to human health.moved about much, the smaller tanks that people with
The fluorine compounds that most people come intoemphysema, asthma or cystic fibrosis often carry
contact with are very solidly bonded to otheraround on carts are the ones that have the highest
chemicals before most people ever come near. Aslikelihood of suffering damage that could be
such, they are mostly inert by definition - somethingcatastrophic if the correct inert lubricants weren't used
that petroleum-based hydrocarbons certainly cannoton newly exposed surfaces.
claim.Industrial gas supplies (whether noble or highly reactive
Among the most useful attributes of fluorochemicalgases) are not usually nearly as mobile or prone to
based oils are their ability to remain non-reactive inshock damage. However, large tanks can go
even the most critical and potentially reactive situationunmaintained for a long time. Along with the use of
involving gases such as pure, high-pressure oxygennon-reactive, synthetic lubricants, it is recommended
situations or other cryogenic gases that are commonlythat any gas tank be maintained on a regular schedule,
used for a wide array of functions.by trained professionals.
Anyone familiar with the highly reactive nature ofIt doesn't matter whether you risk blowing yourself up
gases under high pressure or stored as super-colda little or a lot - such inspections can spot areas that
liquids knows that every single surface that suchare in actual danger from explosion or springing a leak
gases come into contact, whether on purpose orin a line that's been compromised at connection points,
accidentally in the case of mechanical failure of thefittings or bearings. High-pressure oxygen compatible
delivery device components, must not be composedsystems usually have authorized service personal that
of reactive substances.show up on a fixed schedule to care for and maintain
The gas most commonly used and stored in this waythe inside, outside and feeder lines, as per oxygen
is oxygen. Though perhaps most often found insafety guidelines. Those who care for their own
medical applications, SCUBA divers, mountaineers andportable gear should be very careful not to attempt to
high level athletes all use portable liquid oxygen tankstinker with it but instead take the apparatus in for
to deliver pure gaseous oxygen. Safety with suchregular inspections or tune-ups.
devices goes well beyond a smoking ban.The use of fluorochemical non-reactive and inert oils in
Since mechanical devices are responsible for mixinghigh pressure and high performance gas delivery
and delivering oxygen or other reactive gasses undersystems has revolutionized the applications that can
high pressure, an oxygen compatible delivery systemsafely utilize high pressure gases. The added safety
requires inert oils such as the completely fluorinated orhas likely saved scores of lives since inert lubricants
polychlorotrifluoroethylenes (PCTFE) based oils,became commonplace in industry and hobby
lubricants and waxes that keep moving parts fromequipment.